Structural properties and enthalpy of formation of magnesium hydride from quantum Monte Carlo calculations

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Structural properties and enthalpy of formation of magnesium hydride from quantum Monte Carlo calculations

M. Pozzo1 and D. Alfè1,2,3,* 1Department of Earth Sciences and Materials Simulation Laboratory, University College London, Gower Street, London WC1E 6BT, United Kingdom 2Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, United Kingdom 3London Centre for Nanotechnology, University College London, 17-19 Gordon Street, London WC1H 0AH, United Kingdom Re...

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Quantum Monte Carlo calculations of the structural properties and the B1-B2 phase transition of MgO

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We determine the equation of state of stoichiometric FeO by employing the diffusion Monte Carlo method. The fermionic nodes are fixed by a single Slater determinant of spin-unrestricted orbitals. The calculated ambient-pressure properties (lattice constant, bulk modulus, and cohesive energy) agree very well with available experimental data. At approximately 65 GPa, the atomic lattice changes fr...

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ژورنال

عنوان ژورنال: Physical Review B

سال: 2008

ISSN: 1098-0121,1550-235X

DOI: 10.1103/physrevb.77.104103